The Curie temperature is the
temperature above which ferromagnetic materials lose their permanent magnetic
field; the magnetism completely disappears.
Above this temperature the material
behaves paramagnetically. As the temperature rises, the molecular excitement
gradually disrupts the spin alignment. When the Curie temperature is reached
the alignment collapses because the thermal energy has exceeded the energy of
the magnetic interaction.
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| Curie temperature is named after Pierre Curie (1859-1906). |
It is difficult to measure the Curie
temperature exactly. For one thing, the permanent magnetic field around the
material only partly disappears. Secondly, the Curie temperature varies greatly
based on even small quantities of contaminants in the material.
For example, if an AlNiCo magnet is
heated above its Curie temperature of 850 °C, it will no longer be
ferromagnetic. It then becomes paramagnetic. Once the magnet has cooled off
again, the permanent magnetic field does not return. There will, however, be
new magnetic fields present in small areas within the material, the so-called
Weiss areas (Weiss 1865-1904), but these fields are aligned in random
directions so their vector sum does not result in an external magnetic field.
Nevertheless, it is possible to remagnetize the magnet.
The ferromagnetic elements and alloys
with their Curie temperatures:
|
Material
|
|
Curie temp.
|
|
Fe
|
|
770°C
|
|
Co
|
|
1115°C
|
|
Ni
|
|
354°C
|
|
Gd
|
|
19°C
|
|
AlNiCo
|
|
850°C
|
|
Ferrite
|
|
450°C
|
|
Sm Cobalt
|
|
750-825°C
|
|
Nd-Fe-B
|
|
310-340°C
|


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